While all resources in Valheim take an investment of time and effort to uncover and use, Iron is particularly tough to come by. You'll get to it about halfway through your quest through the game, but unlike Copper and Tin, which you'll use to make Bronze for weapons and armor, Iron isn't available to mine at first. Instead, you can only find Iron in specific places in the Swamp biome, and it's impossible to unlock those locations without taking down the boss of the Black Forest, The Elder.
Here's everything you need to know to harvest Iron, including where you can get it, what you need to do to earn it, and what you can turn it into once you have it.
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Now Playing: Valheim First-Person Mod Gameplay
To hang in the Swamp, you're going to want to invest in Bronze armor. Once you've defeated Eikthyr, Valheim's Meadows boss, you'll gain the Hard Antler, which you can turn into a pickaxe. Use that to mine Tin (found near water) and Copper (found in the Black Forest), which you can combine at a Forge to make Bronze. Combined with leather, you can make Bronze clothing that will offer a lot more protection than the Leather and Troll armor you've probably been wearing. You'll also want to invest in Bronze weapons and a Finewood bow.
Once you've got better gear, start searching for Swamps. These dark areas border the ocean and are marked by sparse trees and muddy areas that are tough to traverse. You don't just want any Swamps, though--you're searching for dungeon structures in the Swamp called Sunken Crypts. You won't be able to enter these right away, but mark them on your map because they're your focus when you go hunting for Iron.
The Elder holds a Swamp Key, which you'll need to enter the locations where you can find Scrap Iron.
Destroying the Elder gets you a Swamp Key, which you'll need to actually locate the Iron that's hidden in any Swamp area. The Swamp Key can open the aforementioned Sunken Crypts, the only places where you can find Iron at this point in the game. You'll also need the key to find and take down Bonemass, the Swamp biome boss and the next target on your hitlist.
You won't find Iron anywhere else but in Sunken Crypts at this stage in the game. You'll know these Swamp dungeons by their green torches.
You'll find Scrap Iron in two locations within Sunken Crypts--first, in the various chests that are scattered through these dungeons, and second, in Muddy Scrap Piles. The latter are big black piles of goo in Sunken Crypts, usually blocking doorways. You can smash through them with your pickaxe, although you'll find that the Hard Antler Pickaxe will require fairly regular repairs as you go.
You'll need a Smelter, a Kiln, and a Forge upgraded to Level 2 if you want to make Iron weapons and armor.
If you're employing portals in your adventures, you'll also want to note that metals like Scrap Iron can't be carried through them--you'll have to walk or sail with your Iron haul to bring it to other locations. Because of this, it's a good idea to try to find Swamps with several Sunken Crypts and build an outpost base near them where you can do your Iron forging. You can travel through portals with armor and weapons, but not with metals that haven't been forged yet--so save yourself a lot of marching or sailing by making your gear near where you find your Iron and use portals to travel instead.
With Iron gear, you should be strong enough to take on Bonemass. Defeating it will earn you the Wishbone, which you can use to find buried Iron outside of Sunken Crypts. You'll also need it to locate Silver, the next metal you'll require to amplify your gear.
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